Evaluation of particle size of positive electrode active material

Introducing examples of measurement cases for important management items in the production of lithium-ion batteries and all-solid-state batteries!

We would like to introduce a case of particle size measurement of cathode active materials using laser diffraction conducted by our company. In air or liquid, laser light is irradiated onto particles, and the angular dependence of the intensity of light scattered by the particles is measured. The angular dependence of the scattered light intensity is measured, and from that data, the particle size distribution (particle size distribution) is calculated. Commercially available reagents were used as samples, and measurements were conducted in a dry state without dispersing in a solvent. The particle size measurement results for NMC oxide showed a monodisperse state with particle sizes below several tens of micrometers, and the median diameter was calculated to be 12 μm. 【Case Overview】 ■ Measurement Method ・Dry ■ Particle Size Measurement Results for NMC Oxide ・Monodisperse state with particle sizes below several tens of micrometers ・Median diameter is 12 μm *For more details, please refer to the PDF document or feel free to contact us.

• Other measurement, recording and measuring instruments
• Laser microscope

Determine particle size and particle size distribution! Example of measuring the particle size of silica and alumina particles in an aqueous medium.

Dynamic light scattering allows for the measurement of particle size and size distribution of nanoparticles dispersed in a liquid without separating the particles. Here, we present an example of measuring the particle size of silica and alumina particles in an aqueous medium. Particles in a solution exhibit Brownian motion that depends on their size, and the fluctuations in the scattered light produced when the particles are illuminated depend on their size as well. By observing and analyzing these fluctuations, we can determine the particle size and size distribution. [Alumina Measurement Results and Discussion] - As alumina approaches neutrality from strong alkaline conditions, it nears its isoelectric point. - The surface charge of the particles decreases. - The repulsion between particles diminishes. - It can be inferred that particle aggregation is occurring. *For more details, please refer to the PDF document or feel free to contact us.*

• Contract measurement

The purity of the electrolyte greatly affects the performance of the battery! It suppresses the volatility of sulfur components and converts them into a form that can be detected by IC.

We would like to introduce an example of analyzing the purity of phosphorus pentasulfide using ion chromatography for the composition analysis of raw materials for all-solid-state batteries. Phosphorus pentasulfide is one of the raw materials used in the production of electrolytes for sulfide-based all-solid-state batteries. As a pretreatment for IC measurement, the powder of phosphorus pentasulfide was dissolved in alkaline water and converted into phosphate and sulfide salts. Subsequently, sulfide ions were oxidized to sulfate ions to prepare the IC measurement solution. For more details, please refer to the published catalog. 【Solid Electrolytes (Partial)】 ■Li3PS4 ■Li7P3S11 ■Li6PS5Cl ■Li6PS5Br *For more information, please refer to the PDF materials or feel free to contact us.

• Analytical Equipment and Devices

We exhibited a booth at the "4th Annual Meeting of the Japanese Society for Antibody Research" held at Omiya Sonic City from December 1 (Monday) to December 3 (Wednesday). Thank you very much to everyone who visited our booth during the event. Thanks to your support, we were able to successfully conclude the meeting. If you have any questions regarding the products you viewed, please feel free to reach out to us. We will respond to inquiries received during the event in due course. We appreciate your continued support of Higuchi Shokai. ▼Exhibited Products - Various assembly parts (bags, bottles, sampling, etc.) - Depth filters (post-culture filtration)

We will be exhibiting at the "Adhesive and Adhesive Technology Exhibition 2025" held this Friday, December 12, at the Osaka Industry Creation Center (Sansoukan). Under the slogan "It's natural to stick. Ideas that expand by foaming. Unprecedented concepts," we will showcase our foaming hot melt applicator "MICRON+FOAM" with a focus on foaming adhesion. We plan to distribute coating samples, so please be sure to stop by our booth.

● This is a leak testing device for small electronic components that does not use fluorinated inert liquids (PFAS-free). ● There is no longer a need for unstable visual confirmation through liquid immersion testing. It adopts a quantitative testing method that allows for stable pressure leak testing. ● It is a tabletop leak testing device specifically for gross leaks, with accuracy equal to or greater than that of liquid immersion testing. ● The detectable range is approximately 1×10⁻² Pa·m³/s to 1×10⁻⁶ Pa·m³/s (varies depending on the target product). ● It is suitable for sealed structures ranging from a few millimeters to a maximum of 80 × 70 mm. Please feel free to contact us for more information!

The "Mechanical Stitch Method" by Nichinichisui Road Machinery Co., Ltd. is a new technique that allows for the repair of metal cracks without the application of heat. By using special bolts and reinforcement plates, cracks are physically removed, and repairs are made without causing any thermal impact to the base material. Repairs can be carried out in environments where open flames cannot be used. Since no heat is applied, the disassembly of equipment is minimized. ◎ For more details, please contact us. ◎ If a detailed technical explanation is needed, please contact us.

Do you have any concerns or requests regarding wired bed exit sensors? × Tangling and tripping of wired cables × Cable disconnection or damage × Worry about forgetting to turn on the switch after temporarily stopping the sensor. × Want to be notified of bed exit even from a location away from the nurse call outlet. Such concerns can be resolved simply by connecting to a wireless set linked to the nurse call system! Our nurse call linked wireless set allows you to connect bed exit sensors like "Ugo-kun," "Foldable Thin Matta-kun," "Ayumi-chan," and "Just Place Pole-kun" to transmitters and receivers, reducing wiring around the bed, alleviating concerns about tripping and falling due to cables, and contributing to a tidier work environment. Furthermore, it enables the use of bed exit sensors even from locations away from the nurse call outlet, allowing for more flexible equipment placement.