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catalyst×埼玉大学 - メーカー・企業と製品の一覧

catalystの製品一覧

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Changing the shape of molecules freely with the power of electricity and catalysts.

Electrochemistry, catalyst, (bio) alcohol, aldehyde, ester, acetal, carbon neutral, renewable energy, hydrogen.

By slightly adjusting the shape of a molecule, its function can change dramatically. For example, ethanol brings about a pleasant intoxication, but acetaldehyde, which is derived from ethanol by removing two hydrogen atoms, is the source of hangovers. Industrially, functional molecules such as aldehydes and esters are synthesized from alcohol as a raw material, helping to create products around us. Until now, alcohol has been converted using heat (obtained by burning fossil resources) and oxidants (reagents that pull out hydrogen), but the combustion of fossil resources leads to carbon dioxide emissions, and oxidants generate a large amount of waste. We are pioneering a new alcohol conversion process driven by "electric power" generated from sources like solar power. The key lies in catalytic membranes and ion exchange membranes. By working together, these can create high-value-added molecules from alcohol. This reaction also simultaneously produces hydrogen, which is the next-generation energy source.

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Development of next-generation catalysts utilizing elemental properties!

Keywords: typical element chemistry, organometallic chemistry, element properties, precision polymerization reactions, transition metal-free catalysts, chemical conversion of carbon dioxide.

The creation of "new chemical species" that do not exist in conventional contexts allows for the simultaneous elucidation of new properties such as bonding, structure, and reactivity, as well as the clarification of the new reactivity they confer. In particular, composite compounds that combine main group elements and transition metals generate unique "elemental characteristics" between the elements, enabling the creation of highly active catalysts and highly reactive chemical species. As examples of such "elemental characteristics," we have worked on (1) the development of precision olefin polymerization catalysts and (2) the synthesis of low-coordinate compounds of high-period group 14 elements (tetrelens). In (1), we achieved high activity that surpasses conventional catalysts and successfully produced polyolefins with controlled stereostructures. In (2), the synthesized tetrelens exhibited unique coordination behavior towards transition metals and were found to be usable as alternatives to rare transition metal catalysts. Currently, we are challenging the development of catalysts that enable the conversion reactions of carbon dioxide into useful chemical products using tetrelens.

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