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  6. What are trivalent chromium and hexavalent chromium?

What are trivalent chromium and hexavalent chromium?

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last updated:Feb 14, 2024

シルベック 本社工場
シルベック 本社工場
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Technologies utilizing trivalent and hexavalent chromium.

If you are involved in surface treatment, the first thing that comes to mind when you hear "chromium" is likely hexavalent chromium compounds. Hexavalent chromium compounds are regulated substances under the RoHS Directive and REACH regulation for SVHC (Substances of Very High Concern), so many of you may be familiar with them from product substance investigation lists. On the other hand, the chromium used in surface treatment is not limited to hexavalent chromium compounds. Chromium nitrate and chromium chloride are classified as trivalent chromium compounds. Metallic chromium is zero-valent chromium, which is relatively gentle on the human body and less likely to cause metal allergies. While trivalent chromium compounds are chemical substances and are not inherently safe, if they come into contact with the skin, washing them off immediately will not cause ulcers, and they are not listed as carcinogenic substances. The issue lies with hexavalent chromium compounds, which can cause lung damage if inhaled, gastrointestinal issues if ingested, and are considered carcinogenic. If you have any questions or concerns, please feel free to contact us. 【Contact Information】 TEL: 048-994-5931 FAX: 048-994-5935 E-mail: info@silvec.co.jp

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What are trivalent chromium and hexavalent chromium?

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Chrome plating - Chrome plating using hexavalent chromium compounds = Hexavalent chromium compound-free (compliant with RoHS directive = acceptable) This chrome plating reduces hexavalent chromium compounds to zero-valent metal for deposition, so the plating film does not contain hexavalent chromium compounds. Trivalent chrome plating - Chrome plating using trivalent chromium compounds = Hexavalent chromium compound-free (compliant with RoHS directive = acceptable) Chrome plating using trivalent chromium compounds such as chromium chloride or chromium sulfate also reduces trivalent chromium compounds to zero-valent for deposition, so the plating film is made of chromium metal and does not contain either trivalent or hexavalent chromium compounds. Hexavalent chromium chromate - Hexavalent chromium chromate (conversion coating applied over zinc plating or aluminum) = Contains hexavalent chromium compounds (compliant with RoHS directive = not acceptable) The chromate coating, which is a conversion treatment using hexavalent chromium compounds, generates a film containing hexavalent chromium compounds on the surface of zinc or aluminum to achieve corrosion resistance. This film contains hexavalent chromium compounds. → Silvec does not handle hexavalent chromium chromate.

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Hexavalent chromium and trivalent chromium (What is the difference between chrome plating and chromate?)

Hexavalent chromium and trivalent chromium (What is the difference between chrome plating and chromate?)

TECHNICAL
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Environmental-related investigation certificate [Compliance with RoHS Directive]

Environmental-related investigation certificate [Compliance with RoHS Directive]

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Plating for automotive entry key fittings [One-stop service is also available.]

Plating for automotive entry key fittings [One-stop service is also available.]

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High-precision barrel plating [for fine items and complex shapes!]

High-precision barrel plating [for fine items and complex shapes!]

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シルベック

シルベック 本社工場

Other manufacturing

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Silvec Co., Ltd. (Head Office Factory: Yashio City, Saitama Prefecture) has a strong expertise in plating and surface treatment for various aluminum, aluminum die-cast, and zinc die-cast components, and we supply our products to customers nationwide. We are also skilled in precision barrel plating for fine parts. We have a surface treatment factory in Thailand (Chonburi Province) for plating, anodizing, and chemical treatment as our overseas subsidiary. We offer a one-stop service from material procurement to surface treatment through our extensive network. If you have any inquiries regarding surface treatment for metals, we can provide some suggestions. Please feel free to contact us.

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