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  6. Technical Data: Constant Voltage Intermittent Titration Method (PITT)

Technical Data: Constant Voltage Intermittent Titration Method (PITT)

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Electrochemical measurement device (potentiostat-galvanostat)

last updated:Jun 09, 2026

メトロームジャパン 本社
メトロームジャパン 本社
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The potentiostat intermittent titration technique (PITT) is one of the most commonly used methods to gain insights into the diffusion coefficients of electrode active materials.

During the charging and discharging of lithium-ion batteries (Li-ion batteries), lithium ions are transported from one electrode through the electrolyte to the other electrode. Knowing the chemical diffusion coefficient of the electrode materials is very important. The potentiostat intermittent titration technique (PITT) is one of the most commonly used methods to gain insights into the diffusion coefficients of electrode active materials.

    Secondary Cells/BatteriesLithium-ion batteryOther electric meters
EC-AN-BAT-004-JP-定電位間欠滴定法PITT-ver2-image.jpg

Technical Data: Constant Voltage Intermittent Titration Method (PITT)

EC-AN-BAT-004-JP-定電位間欠滴定法PITT-ver2-image.jpg
EC-AN-BAT-004-JP-定電位間欠滴定法PITT-ver2-image.jpg MultX_5620.jpg
  • Related Link - https://www.metrohm.com/ja_jp/products/electrochem…
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basic information

Li-ion batteries are one of the most researched energy storage devices due to their relatively high energy and power performance. During the charging and discharging of Li-ion batteries, Li ions are transported from one electrode to the other through the electrolyte. Here, diffusion of Li ions into the bulk material occurs. In this regard, the diffusion coefficient of the active material present in the electrode directly affects battery performance. Therefore, knowing the chemical diffusion coefficient of the electrode material is extremely important. The potentiostatic intermittent titration technique (PITT) is commonly used in conjunction with its galvanostatic counterpart, GITT, to gain insights into the diffusion coefficient of the active material in the electrode.

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I am measuring using the PGSTA302 from Metronome Autolab.

Detailed information

  • Autolab_PGSTAT302N,-ECAT-complete_4487_550X366.jpg

    PGSTA302N Potentiostat/Galvanostat

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Technical Data: Constant Voltage Intermittent Titration Method (PITT)

Technical Data: Constant Voltage Intermittent Titration Method (PITT)

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Technical Data: Galvanostatic Intermittent Titration Technique (GITT)

Technical Data: Galvanostatic Intermittent Titration Technique (GITT)

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Comprehensive Catalog of Electrochemical Measurement Devices (Potentiostat/Galvanostat)

Comprehensive Catalog of Electrochemical Measurement Devices (Potentiostat/Galvanostat)

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Electrochemical Measurement Device DropSens Product Catalog (Potentiostat/Galvanostat)

Electrochemical Measurement Device DropSens Product Catalog (Potentiostat/Galvanostat)

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Electrochemical measurement device (potentiostat/galvanostat)

Electrochemical measurement device (potentiostat/galvanostat)

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Multi-channel electrochemical measurement device (potentiostat/galvanostat) μStat-MultiX

Multi-channel electrochemical measurement device (potentiostat/galvanostat) μStat-MultiX

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Battery/Fuel Cell Analysis Device Guide

Battery/Fuel Cell Analysis Device Guide

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List of applications for battery research and quality control.

List of applications for battery research and quality control.

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Technical Document 8 of Raman Spectroscopy: Elucidation of Batteries Using EC-Raman Solutions

Technical Document 8 of Raman Spectroscopy: Elucidation of Batteries Using EC-Raman Solutions

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Company information

メトロームジャパン

メトロームジャパン 本社

Testing, Analysis and Measurement

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Metrom AG, based in Herisau, Switzerland, is a leading company specializing in ion analysis with over 70 years of history. It provides products and services in more than 140 countries worldwide. Based on Swiss technology developed over many years, the equipment comes with a 3-year warranty.

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